D'nal Boone (closer to the way they pronounced it) just didn't like it when anyone got to live within a few miles of his house, so he kept moving. One of the people who pioneered the way through the Cumberland Gap so the people from the East Coast could move to KY, he ended up cross the Mississippi, in Boone's Lick I think.
And, the number one maker of bourbon, Jack Daniel's Distillery, (Which has the #1 U.S Government permit to distill whiskey, in 1866) is located in Lynchburg, a place where it can't be sold. Odd. But Lynchburg is in Tennessee, not Kentucky, given that, I doubt that KY makes 95% as I bet the market share of all JD products is above 5%.