Get a haircut. No, really.
I had nothing but straight long hair my whole life. I finally went to the girl who does my brows (hurray english speaking salons) and told her to do whatever she wanted to with my hair, just get rid of it and make me sexy. That makes a stylist wet, when they have a large, open canvas.
A few weeks later I decided it was still too long, and had her go with the nuclear option and give me bangs and even shorter hair.
I really love it.
You don't have to hack off your hair, but, that hair cut does not work for your face at all. You need layers to frame the face and you need bangs for the forehead (and more shaped brows, but that's another matter.)
It feels violating, coming from a male life, especially one with a gender disorder, to cut your hair. Hair is the strongest and most accepted symbol of femininity in men, something held onto. Also, considering how many lose their hair, it's traumatic, especially for MTF. But less can be a lot more. The 'curtain' as my stylist said, just kind of hangs there. And with it hanging down in front of your ears, it gives you a long, male face.
Of course, a flat out girl's haircut where you have to style your bangs and maybe some other parts of it (I'm still playing around with hot curling and some product) may draw attention and ire. But it will help tremendously.
Learn makeup slowly. Use browns and bronzes instead of blacks to start with. Eye makeup actually involves coloring the lid, the crease, and the bone above (and maybe your cat's eyes and using a primer before hand) and liner and curling your lashes and mascara (be sure to curl before you do anything else.) It's not typically just *block of black* unless you are going for a marilyn manson look, but I imagine your ultimate goal is not.
My personal philosophy when I began exploring makeup was that when I sucked at it, I looked a LOT worse than not wearing it. Something about poorly done makeup screams transvestite.
Also you may try to improve your overall skin health with cleansing/exfoliating/toning/moisturizing, if you don't already have a strict skin care system. When you go on E, your skin will dry out, which will end most of the acne (as long as you change your pillow case.... *grumble, 4 scars from that...*) but require even more moisture.
Also be sure you thoroughly clean and moisturize after wearing makeup. Eye makeup remover, if you don't have it, is gentle and awesome, and makeup remover wipes are fantastic too. And you can always add more, it's much harder to remove, so start light with the makeup.
I don't even try eye liner, still, honestly, because I'm a moron when it comes to it and I don't want to embarrass myself.