Not entirely sure what you mean by "female orgasm"; You might have to operationally define that for us. You could be talking about any number of things really, but given that you put this in the "Androgyne" forum rather than the "transgender (general)" or MtF/FtM ones, I'm willing to bet you might have had female-bodied/mostly female-leaning genderqueer individuals in mind. And even then, there are several different ways to achieve orgasm even among those with XX chromosomes, so I'm STILL not entirely sure what you mean.
I am XX pre-anything, and yes, I have had several orgasms before since my first accidentally-achieved one about five to six years ago, all self-brought. Although probably 90% of those have been achieved by external stimulation alone, and not a single one has been from solely penetration; I've actually found that it is impossible for me to orgasm via solely penetration. Most of that 10% came from a stage early in my sexual self discovery where I felt incompetent and needed to "practice" in order to "prepare" myself for future sexual partners, and so I forced myself to use toys, even if the same result could have been achieved with just a rag (since socks don't fit me, obviously) and could have in some cases had less unpleasant side effects. My results have varied before: Sometimes the toys actually add something that I wouldn't have gotten from external alone, and sometimes they just freak me the heck out and I "nope" too hard at even the idea of it to try. Having paid attention recently, I really do think it is connected closely to my identity trends. I find I'm more open to using toys when I'm also more open to presenting in a feminine way in public. I also don't really consider it, and if I do the idea is just "meh, why not" or "I'm too lazy", when I feel more comfortable presenting more neutrally in public. But when I really want to present in a more masculine way in public, usually, I won't even entertain the idea for a second. In those cases I just do my thing the way any cis guy would; the only difference being I have much less to grab at.
So for me, the answer is yes and no; it really depends on how I'm feeling at the time as to whether or not I'm up for orgasming via "female" methods.