If I were you, if you can, speak to your brother and ask him if he has said anything to his girlfriend and what. Maybe he has explained it to her and shes fine with it all, that could possibly work out best if you present as male and your other brother uses the wrong pronoun, atleast she will understand what is going on.
And/or you could speak to your other brother too and remind him of everything and politely tell him you need him to go back to male pronouns.
I have been in similar situations. One was when I was 15, not on T, out to my immediate family, but not able to live as myself or introduce myself properly. I still dressed like a guy though, so I passed to people who didnt know me/didnt hear my immediate family using the wrong pronouns about me

We went to my Aunts birthday party, just to say hi and whatnot. There was a distant cousin Id never met before, he was probably in his late 20s. Basically, we all were chatting, I could tell he completely read me as male, and because I just said hi, but wasnt in the conversation,nothing came up to "out" me to him.
About a year ago, (Im completely stealth and living as male by now) Im out at a bar, and I bump into the distant cousin and he recognizes me and starts being really friendly and acting like weve been mates for ages. He seemed a cool guy, but also like he would not have understood/been friendly had he first viewed me as female and then seen me all masculinized, I could just tell he is like that.
Anyway, although my family didnt actually help by using my chosen name and pronouns, by not using the wrong ones, I was able to present fully as male which saved me trouble and awkwardness 4 years later!
So, I think it is best to try to get your family to help you out here. Speak to them.
Good luck.