I'll mostly echo what other guys have said--- zinc won't do a thing to help you masculinize. Exercise, particularly weight lifting, will help increase your T levels, though, and coupling it with a high-protein, low-carb diet will do the most. Keep your carb intake restricted to the day, and don't eat any carbs or sugar after about 3 pm. Flax seed helps as well--- oil, pills, or seeds themselves. Some herbal/vitamin stores carry supplements that claim to raise T levels, but as with most homeopathic medicine, they're ungrounded claims--- I haven't found any reliable accounts from ftms saying that those work.
Of course, zinc is always good for overall health. As with any vitamin or mineral, though, make sure you're not overdosing yourself on it.